Sirvi Autor "Ojakivi, Mari" järgi

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    Charged Droplets – Novel Media for Studying Reactions between Aldehydes and Amines/Hydrazines
    (Tartu Ülikool, 2019) Ojakivi, Mari; Kruve-Viil, Anneli; Liigand, Jaanus; Tartu Ülikool. Loodus- ja täppisteaduste valdkond; Tartu Ülikool. Keemia instituut
    Within the framework of this study, reactions between 7 aldehydes and 4 nitrogen bases were carried out in charged droplets. For this, an in-house built electrospray system was designed and built. For comparison, the same reactions were also carried out in bulk phase under similar conditions. The results show, that charged droplets are a new potent media for carrying out reactions, since the reactions were accelerated compared to bulk phase. Also, new reaction pathways may be found, as several new products were observed.