High energy density Zn-ion hybrid capacitor using non-aqueous electrolytes
Date
2023
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Tartu Ülikool
Abstract
Intensive research in the field of supercapacitors has been fuelled by the need for high
efficiency energy storage systems. The concept of hybrid capacitor aims to close the gap
between batteries and electrical double-layer capacitors in terms of improving the energy
density. The purpose of the study was to find out if Zn-ion hybrid capacitors have the necessary
characteristics and properties to be alternative future energy storage technology.
Different combinations of acetonitrile and propylene carbonate solvents, together with
Zn(TFSI)2, Zn(BF4)2 and Zn(OTf)2 salts were tested. Zn and carbon cloth electrode were
studied using different physical characterization methods. Electrochemical performance for
assembled test cells was measured and compared using cyclic voltammetry, electrochemical
impedance spectroscopy, constant current charge/discharge methods and Ragone plots.
Acetonitrile-based systems exhibited promising electrochemical results.
Description
Keywords
coulombic and energy efficiency, non-aqueous electrolyte, fibrous carbon cloth electrode, Zn thin foil electrode, Zn-ion hybrid supercapacitor